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Lead Acid Battery Degradation-
Lead acid is a flow battery
The electrochemistry of static lead-acid and soluble lead-acid flow batteries is summarised and the differences between the two batteries are highlighted. A general comparison of the performance of an un.
FAQs about Lead acid is a flow battery
What is a soluble lead-acid flow battery?
A scaled-up soluble lead-acid flow battery has been demonstrated, operating both as a single cell and as a bipolar, two-cell stack. Using short charge times (900 s at ≤20 mA cm −2) the battery successfully runs for numerous charge/discharge cycles.
What causes a soluble lead-acid flow battery to fail?
Following a large number of charge/discharge cycles, a soluble lead-acid flow battery could fail due to cell shorting caused by the growth of lead and lead dioxide deposition the negative and positive electrode, respectively.
What is a soluble lead acid battery?
As a flow battery, the soluble lead acid battery is also unique in that no microporous separator (typically a cation-exchange membrane such as Nafion) is required and a single reservoir is used for the electrolyte, allowing for a simpler design and a substantial reduction in cost.
What is the difference between soluble and Static lead-acid battery?
Conclusions 1. The electrochemistries of the soluble lead-acid flow battery and the static lead-acid battery are distinctly different; in the soluble lead acid battery lead is highly soluble in the electrolyte of methanesulfonic acid, while lead is a solid paste in the static lead-acid battery.
Does soluble lead-acid flow battery self-discharge?
Self-discharge was also observed in the case of the soluble lead-acid flow battery when it was left open-circuit for a long time period. To test the self-discharge characteristic of a soluble lead-acid flow battery, a series of charge/discharge cycles were performed.
How do lead-acid batteries work?
Traditional lead-acid batteries (e.g., SLI, starting lighting ignition) batteries for automotive applications) operate with an electrolyte, typically sulphuric acid, in which lead compounds are only sparingly soluble. Consequently, an insoluble paste containing the active materials is normally applied to each of the electrodes.
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Electric car lithium battery lead acid battery
Lead acid and lithium-ion batteries dominate the market. This article offers a detailed comparison, covering chemistry, construction, pros, cons, applications, and operation.
FAQs about Electric car lithium battery lead acid battery
Are lead-acid batteries good for electric cars?
Lead-acid batteries are the oldest technology and have the shortest lifespan, making them less popular for electric cars. Ultimately, each type of battery has its own pros and cons, and it's important to consider factors like cost, lifespan, and energy efficiency when comparing electric car batteries.
Are lithium-ion batteries lighter than lead-acid batteries?
Lithium-ion batteries are lighter and more compact than lead-acid batteries for the same energy storage capacity. For example, a lead-acid battery might weigh 20-30 kilograms (kg) per kWh, while a lithium-ion battery could weigh only 5-10 kg per kWh.
What is the difference between lithium ion and lead acid batteries?
The primary difference lies in their chemistry and energy density. Lithium-ion batteries are more efficient, lightweight, and have a longer lifespan than lead acid batteries. Why are lithium-ion batteries better for electric vehicles?
Why are lead-acid batteries better than Li batteries?
On contrary, lead is a carcinogenic material that is harmful to the environment. Even lead-acid batteries contain other chemicals such as sulphuric acid that are poisonous. But the recycling rate for lead-acid batteries is higher than Li batteries. Also, lead-acid batteries are cheaper because of their wide availability.
Why are lead-acid batteries important?
Lead-acid batteries remain an essential component in the battery industry. Despite not matching the energy capacity of newer batteries, their reliability, low cost, and high current delivery make Lead-acid batteries invaluable for certain uses.
How does a lead acid battery work?
2. Lead-Acid Batteries: Working: Lead-acid batteries utilize lead dioxide as the cathode and sponge lead as the anode immersed in a sulfuric acid electrolyte. During discharge, lead and lead dioxide react with sulfuric acid to produce electricity.
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Battery Indicator Lead Acid
The liquid-filled lead acid batteries used in automobiles and a range of other products have many great qualities, but are also known to “go bad” with little warning. Fortunately, you can easily do a basic health checkup on any.
FAQs about Battery Indicator Lead Acid
How do lead acid batteries recharge?
Lead acid batteries recharge in various manners based on their function and manner of installation. For a lead acid vehicle battery, drive the vehicle around for at least 20 minutes. For a lead acid battery connected to solar panels, let the battery charge fully on a sunny day.
How do you check a lead acid battery?
Fortunately, you can easily do a basic health checkup on any type of lead acid battery by hooking it up to a simple-to-use digital voltmeter. If you have an open-cell battery that lets you access the liquid inside, you can do a more rigorous checkup with a battery hydrometer. Charge the battery fully, then let it rest for 4 hours.
Do lead acid batteries go bad?
The liquid-filled lead acid batteries used in automobiles and a range of other products have many great qualities, but are also known to “go bad” with little warning. Fortunately, you can easily do a basic health checkup on any type of lead acid battery by hooking it up to a simple-to-use digital voltmeter.
What is a lead-acid battery?
Lead-acid batteries are a type of rechargeable battery that uses lead and lead oxide electrodes submerged in an electrolyte solution of sulfuric acid and water. They are commonly used in vehicles, backup power supplies, and other applications that require a reliable and long-lasting source of energy.
How do you know if a lead-acid battery is healthy?
To get a more accurate reading of a lead-acid battery's health, you can use a hydrometer. This tool measures the specific gravity of the electrolyte solution within the battery, which can give you a better idea of its state of charge and overall condition. Before using a hydrometer, it's important to make sure the battery is fully charged.
Can you test a lead acid battery with a hydrometer?
Checking an open-cell lead acid battery—that is, a lead acid battery with caps that can be opened to access the liquid inside—with a battery hydrometer is most accurate when the battery is fully charged. Closed-cell lead acid batteries without the access caps cannot be tested this way.
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Battery charging time becomes shorter lead acid
Slower charging occurs when a lead acid battery takes longer to reach a full charge. Aging batteries exhibit increased internal resistance, which impedes the flow of current during charging.
FAQs about Battery charging time becomes shorter lead acid
How fast can a lead-acid battery charge?
Experiments on a 12 V 50 Ah Valve Regulated Lead Acid (VRLA) battery indicated the possibility of 100 % charge in about 6 h, however, with high gas evolution. As a result, the feasibility of multi-step constant current charging with rest time was established as a method for fast charging in lead-acid batteries.
What causes a lead acid battery short circuit?
The following mainly analyzes the lead-acid battery short circuit caused by excessive charging current, charging voltage of a single battery exceeds 2.4V, internal short-circuit or partial discharge, excessive temperature rise and valve control failure, and summarizes the treatment methods of lead acid battery short circuit as follows:
Can lead acid batteries be charged quickly?
Lead acid is sluggish and cannot be charged as quickly as other battery systems. (See BU-202: New Lead Acid Systems) With the CCCV method, lead acid batteries are charged in three stages, which are constant-current charge, topping charge and float charge.
What happens if you don't recharge a lead-acid battery?
Even in storage, lead-acid batteries naturally lose charge over time, and failure to periodically recharge them can result in irreversible damage. 8. Proper Disposal and Recycling of Lead-Acid Batteries Lead-acid batteries contain hazardous materials, including lead and sulfuric acid, making proper disposal crucial.
What temperature should a lead-acid battery be charged at?
Temperature Control: Ideally, lead-acid batteries should be charged at temperatures below 80°F (27°C). Charging at high temperatures can lead to thermal runaway, where the battery overheats and becomes damaged. If your battery becomes hot to the touch during charging, stop the process immediately and allow it to cool. 4. Avoiding Overcharging
How do I charge a lead-acid battery?
The most important first step in charging a lead-acid battery is selecting the correct charger. Lead-acid batteries come in different types, including flooded (wet), absorbed glass mat (AGM), and gel batteries. Each type has specific charging requirements regarding voltage and current levels.
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What is battery acid made of
A lead-acid battery consists of two lead plates separated by a liquid or gel containing sulfuric acid in water. The battery is rechargeable, with charging and discharging chemical reactions. When the battery is being used (discharged), electrons move from the negatively-charged lead plate to the positively-charged plate. The. When the battery is fully charged, the negative plate is lead, the electrolyte is concentrated sulfuric acid, and the positive plate is lead dioxide. If the battery is overcharged, electrolysis of water produces hydrogen gas. Calling sulfuric acid"battery acid" gives an indication of the acid concentration. There are, in fact, several different names for sulfuric acid that typically reflect its usage. 1. Concentration less than.
FAQs about What is battery acid made of
What is battery acid made of?
The battery acid is made of sulfuric acid (H2So4) diluted with purified water to get an overall concentration of around 29-32, a density of 1.25-1.28 kg/L, and a concentration of 4.2 mol/L. The pH value of electrolytes is about 0.8, so we need to take utmost care when handling battery acid. What Is Battery Acid?
Why do batteries contain acid?
Batteries contain acid because it's fundamental to the electrochemical reaction that takes place. Also referred to as battery electrolyte, battery acid is the medium that carries the electrical flow between positive and negative electrodes.
What is car battery acid?
Car battery acid is around 35% sulfuric acid in water. Battery acid is a solution of sulfuric acid (H 2 SO 4) in water that serves as the conductive medium within batteries. It facilitates the exchange of ions between the battery's anode and cathode, allowing for energy storage and discharge.
What is the chemical formula for battery acid?
Battery acid primarily refers to sulfuric acid, with the chemical formula H2SO4. Now, if we break that down, we get two hydrogen atoms, one sulfur atom, and four oxygen atoms working together in harmony to perform a critical role in the battery's operations. Think of it as the fuel that powers the entire battery system. Why Sulfuric Acid?
What is battery acid used for?
Battery acid (AKA sulfuric acid) is used in lead-acid batteries to help create and store electrical energy, which powers many devices and vehicles.
Are acid batteries corrosive?
These batteries are highly corrosive, and react vigorously with the skin, causing burns and irritation. Battery acids have a high electrical conductivity. Usually, these acids are colorless. However, they can easily pick on impurities. The density of an acid battery is twice that of water.
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Battery replacement for sulfuric acid
When your mechanic tells you your battery's electrolyte level is low, it means the fluid level in one or more of the battery cells has dropped below the top of the lead plates. What does that mean? Car batteries are composed of a series of lead plates submerged in a bath of water and sulfuric acid. This creates a chemical. The only electrolyte that can be used in a lead-acid battery is sulfuric acid. Adding anything but water to a battery can instantly damage it, but some substances are worse than others. For example, baking soda can. Water, on its own, is not an electrolyte. It can only be an electrolyte when mixed with sulfuric acid, so it stands to reason that you would have to top. Although you can prolong the life of a lead acid battery by keeping it topped off, leaving it empty, or allowing the charge to drain too low, can cause irreparable harm. Once a battery reaches a.
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FAQs about Battery replacement for sulfuric acid
Can you put sulfuric acid in a car battery?
Do not do this. Never put any kind of electrolyte in a lead-acid car battery. If your battery electrolyte is low, the only thing you should ever add is straight water. There are some specific circumstances where sulfuric acid may be added, such as if the battery has tipped over and leaked, but never add anything else.
How does sulfuric acid work in a lead-acid battery?
Under normal conditions, sulfuric acid in the electrolyte solution is absorbed into the lead plates as the battery discharges power. It is then released back into the electrolyte solution as the battery charges. The only electrolyte that can be used in a lead-acid battery is sulfuric acid.
How do you clean a battery with sulfuric acid?
Inspect the electrolyte level of each battery cell. Tip the battery forward to empty the electrolyte solution from the battery cells. Since the battery electrolyte contains sulfuric acid, make sure to capture all of the used electrolyte solution in an acid-resistant container.
Can you add sulfuric acid if battery electrolyte is low?
If your battery electrolyte is low, the only thing you should ever add is straight water. There are some specific circumstances where sulfuric acid may be added, such as if the battery has tipped over and leaked, but never add anything else. What Does it Mean When Battery Electrolyte is Low?
Can I add diluted sulfuric acid to a battery?
You can add diluted sulfuric acid to a battery in the following situations: New, Dry Batteries: When the battery is shipped dry, it requires sulfuric acid to initiate the chemical reactions necessary for operation. Leakage: If the battery leaks and loses electrolyte, adding acid restores the correct levels.
Which electrolyte can be used in a lead-acid battery?
The only electrolyte that can be used in a lead-acid battery is sulfuric acid. Adding anything but water to a battery can instantly damage it, but some substances are worse than others. For example, baking soda can neutralize the sulfuric acid present in a battery's electrolyte solution.
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Sulfuric acid in the battery
A lead-acid battery consists of two lead plates separated by a liquid or gel containing sulfuric acid in water. The battery is rechargeable, with charging and discharging chemical reactions. When the battery is being used (discharged), electrons move from the negatively-charged lead plate to the positively-charged plate. The. When the battery is fully charged, the negative plate is lead, the electrolyte is concentrated sulfuric acid, and the positive plate is lead dioxide. If the. Calling sulfuric acid"battery acid" gives an indication of the acid concentration. There are, in fact, several different names for sulfuric acid that typically.
FAQs about Sulfuric acid in the battery
What does sulphuric acid do in a battery?
It facilitates the exchange of ions between the battery's anode and cathode, allowing for energy storage and discharge. Sulfuric acid (or sulphuric acid) is the type of acid found in lead-acid batteries, a type of rechargeable battery commonly found in vehicles, emergency lighting systems, and backup power supplies.
How does sulfuric acid affect a car battery?
In automobile batteries, sulfuric acid is combined with water to form an electrolyte. This electrolyte facilitates the chemical process within the battery and enables ions to move freely from one terminal to another. However, sulfuric acid can cause problems, such as damaging vehicles or injuries.
Why is sulfuric acid important in AGM batteries?
The purity and concentration of the sulfuric acid in AGM batteries are critical, as impurities can significantly affect the mat's ability to absorb the electrolyte and the battery's overall performance. As battery technology advances, the demands on the electrolyte become more stringent.
How does sulfuric acid work in a lead-acid battery?
Under normal conditions, sulfuric acid in the electrolyte solution is absorbed into the lead plates as the battery discharges power. It is then released back into the electrolyte solution as the battery charges. The only electrolyte that can be used in a lead-acid battery is sulfuric acid.
What is car battery acid?
Car battery acid is around 35% sulfuric acid in water. Battery acid is a solution of sulfuric acid (H 2 SO 4) in water that serves as the conductive medium within batteries. It facilitates the exchange of ions between the battery's anode and cathode, allowing for energy storage and discharge.
What is battery acid used for?
Battery acid (AKA sulfuric acid) is used in lead-acid batteries to help create and store electrical energy, which powers many devices and vehicles.
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Annual lead emission of lead-acid battery projects
In the CML impact categories, most of the impact (>85 %) was discovered to stem from the production of lead metal, rather than the production of the sheet that results from the lead. An exception to this was ozone depletion potential, which also sees a significant share stemming from sheet production. This can be seen in. Following on from the Lead Sheet LCA study, a socio-economic assessment was conducted using the LCA data (RPA 2014 internal report). Life cycle.
FAQs about Annual lead emission of lead-acid battery projects
What are the environmental impacts of lead based batteries?
Lead-based batteries LCA Lead production (from ores or recycled scrap) is the dominant contributor to environmental impacts associated with the production of lead-based batteries. The high recycling rates associated with lead-acid batteries dramatically reduce any environmental impacts.
What is the life cycle impact of lead acid batteries?
Table 2. Life cycle impact assessment results for 1 kWh lead acid batteries used in e-bikes with an average service life. Energy and resource use. Overall, primary energy use (PEU) totals 4635 MJ for 1 kWh capacity of LABs throughout the life cycle, 84% of which is contributed by electricity consumption in the use stage.
How important is lead production in battery production?
For all battery technologies, the contribution of lead production to the impact categories under consideration was in the range of 40 to 80 % of total cradle-to-gate impact, making it the most dominant contributor in the production phase (system A) of the life cycle of lead-based batteries.
What are the environmental impacts of lead production?
Mining and smelting have the greatest environmental impacts for lead production. The main contributors in mining and concentration are the fuel combustion and power production. Study represented 80 % of production technology but only 32 % of ILA members. Lead-based batteries LCA
Are lead-acid batteries good for the environment?
The high recycling rates associated with lead-acid batteries dramatically reduce any environmental impacts. In terms of global warming potential, the environmental advantage of improved and advanced technology lead-based batteries during the use phase far outweighs the impacts of their production.
What is a lead battery LCA?
The lead battery LCA assesses not only the production and end of life but also the use phase of these products in vehicles. The study demonstrates that the technological capabilities of innovative advanced lead batteries used in start-stop vehicles significantly offset the environmental impact of their production.
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Charging Chemistry of Lead Acid Batteries
What Chemical Reactions Occur During the Charging of a Lead-Acid Battery?Primary reactions: – Conversion of lead sulfate to lead dioxide. Secondary reactions: – Gassing (oxygen and hydrogen evolution).
FAQs about Charging Chemistry of Lead Acid Batteries
How to charge a lead acid battery?
Normally battery manufacturer provides the proper method of charging the specific lead-acid batteries. Constant current charging is not typically used in Lead Acid Battery charging. Most common charging method used in lead acid battery is constant voltage charging method which is an effective process in terms of charging time.
How a lead acid battery works?
Working of the Lead Acid battery is all about chemistry and it is very interesting to know about it. There are huge chemical process is involved in Lead Acid battery's charging and discharging condition. The diluted sulfuric acid H 2 SO 4 molecules break into two parts when the acid dissolves.
What happens during the charging process of a lead-acid battery?
During the charging process of a lead-acid battery, lead dioxide is formed at the positive plate. This process is integral to the battery's ability to store and release electrical energy. Lead-acid batteries, known for their reliability and cost-effectiveness, play a pivotal role in various applications.
What happens if you overcharge a lead acid battery?
Overcharging a lead acid battery is like overeating; it's not good for its health. It can lead to water loss, increased temperature, and even damage. It's essential to keep an eye on the charging process to avoid these issues. Sulfation is a big no-no for lead acid batteries. It's like rust for metal, degrading the battery's performance.
What happens when a lead acid battery is discharged?
Discharging of a lead acid battery is again involved with chemical reactions. The sulfuric acid is in the diluted form with typically 3:1 ratio with water and sulfuric acid. When the loads are connected across the plates, the sulfuric acid again breaks into positive ions 2H+ and negative ions SO 4.
Why is it important to understand the lead-acid battery reaction?
Understanding the lead-acid battery reaction is key to optimizing its performance and longevity. The process of charging and discharging a lead-acid battery is a delicate balance. Proper management of this cycle is essential to maintain the battery's health and ensure its efficient operation.
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Lead battery charging current and voltage
Sealed lead acid batteries may be charged by using any of the following charging techniques: 1. Constant Voltage 2. Constant Current 3. Taper Current 4. Two Step Constant Voltage To obtain maximum battery ser. During constant voltage or taper charging, the battery's current acceptance decreases as voltage and state of charge increase. The battery is fully charged once the current stabilize. Selecting the appropriate charging method for your sealed lead acid battery depends on the intended u. Constant voltage charging is the best method to charge sealed lead acid batteries. Depending on the application, batteries may be charged either on a continuous or no. Constant current charging is suited for applications where discharged ampere-hours of the preceding discharge cycle are known. Charge time and charge quantity can easily be cal.
FAQs about Lead battery charging current and voltage
How to charge a lead acid battery?
The lead-acid battery mainly uses two types of charging methods namely the constant voltage charging and constant current charging. It is the most common method of charging the lead acid battery. It reduces the charging time and increases the capacity up to 20%. But this method reduces the efficiency by approximately 10%.
How do you know if a lead acid battery is charging?
Just multiply the voltages by 2 for 24V or 4 for 48V batteries. The only way to get an accurate reading of a lead acid battery's state of charge from voltage is to measure its open circuit voltage. This means the battery must be disconnected from all loads and chargers and allowed to rest for several hours until its voltage stabilizes.
What voltage should a 48V flooded lead acid battery be charged?
The optimal charging voltage for 48V flooded lead acid batteries is typically around 58V to 62V at the start of charging. Sealed batteries may need slightly higher voltages. Refer to the battery specifications. How Can I Revive a Dead Lead Acid Battery?
What is the ideal charging current for recharging AGM sealed lead acid batteries?
Customers often ask us about the ideal charging current for recharging our AGM sealed lead acid batteries. We have the answer: 25% of the battery capacity. The battery capacity is indicated by Ah (Ampere Hour). For example: In a 12V 45Ah Sealed Lead Acid Battery, the capacity is 45 Ah.
How many amps should a 12V lead acid battery charge?
For example: In a 12V 45Ah Sealed Lead Acid Battery, the capacity is 45 Ah. So, the charging current should be no more than 11.25 Amps (to prevent thermal runaway and battery expiration). Importantly, if you have other equipment connected to the battery during chargning, it also needs to be powered, so you need to add that to your calculations.
How a battery is charged at a constant voltage?
In this method the charging current is high in the beginning when a battery is in discharged condition, and it gradually drops off as the battery picks up charge resulting in increased back emf. Charging at constant voltage may be carried out only when the batteries have the same voltage, for example, 6 or 12 or 24 V.
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Battery grid connection procedure
For the purposes of this document, the following terms and definitions apply; Power Generating Modules are categorised in EREC G99 as Power Park Modules (PPM) or Synchronous Power Generating Modules (SPGM). Both contain one or more. When you are ready to submit a formal application for connection, we will require information from you to enable us to make a reasonable assessment of the works required to facilitate the. Discussing your plans with us at an early stage can help to provide a better insight to any potential network reinforcement and complexity issues that. If you are not ready to enter into a formal agreement for connection works, or you do not yet have full details of the specific conditions required, you.
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Fire safety at lithium battery charging stations
There are several options that can be used in to help mitigate the risk presented by lithium-ion battery charging, they include:Place the battery in an appropriately located fire compartment with access for maintenance and repair. Environmentally controlled environments, to prevent overheating of the space. Provide battery thermal management devices that automatically cut charging if issues detected.
FAQs about Fire safety at lithium battery charging stations
Are lithium-ion batteries a fire risk?
Over the past four years, insurance companies have changed the status of Lithium-ion batteries and the devices which contain them, from being an emerging fire risk to a recognised risk, therefore those responsible for fire safety in workplaces and public spaces need a much better understanding of this risk, and how best to mitigate it.
How do you protect a lithium-ion battery from a fire?
There are several options that can be used in to help mitigate the risk presented by lithium-ion battery charging, they include: Place the battery in an appropriately located fire compartment with access for maintenance and repair. Environmentally controlled environments, to prevent overheating of the space. Fire Detection. Fire Suppression.
Are lithium-ion battery energy storage systems fire safe?
With the advantages of high energy density, short response time and low economic cost, utility-scale lithium-ion battery energy storage systems are built and installed around the world. However, due to the thermal runaway characteristics of lithium-ion batteries, much more attention is attracted to the fire safety of battery energy storage systems.
Does your fire risk assessment cover lithium-ion battery fires?
A survey of more than 500 organisations carried out between September 2023 and February 2024 revealed that 71 per cent of respondents had not updated their fire risk assessments to cover the risk of Lithium-ion battery fires, with just 15 per cent having done so and a further 14 per cent unsure.
Are lithium-ion batteries safe to charge EVs?
This guide focusses on fire hazards and good-practice risk control measures for the charging of EVs using lithium-ion batteries, driven on highways, (i.e. cars, motorcycles, bicycles, lorries, coaches/buses, etc.) Lithium-ion batteries are the predominant type of rechargeable battery used in EVs.
How do you manage a lithium-ion battery hazard?
Specific risk control measures should be determined through site, task and activity risk assessments, with the handling of and work on batteries clearly changing the risk profile. Considerations include: Segregation of charging and any areas where work on or handling of lithium-ion batteries is undertaken.